Molecular Functionalization of 2H-Phase MoS2 Nanosheets via an Electrolytic Route for Enhanced Catalytic Performance.

The molecular functionalization of two-dimensional MoS2 is of practical relevance with a view to, for example, facilitating its liquid-phase processing or enhancing its performance in target applications. While derivatization of metallic 1T-phase MoS2 nanosheets has been relatively well studied, progress involving their thermodynamically stable, 2H-phase counterpart has been more limited due to the lower chemical reactivity of the latter. Here, we report a simple electrolytic strategy to functionalize 2H-phase MoS2 nanosheets with molecular groups derived from organoiodides. Upon cathodic treatment of a pre-expanded MoS2 crystal in an electrolyte containing the organoiodide, water-dispersible nanosheets derivatized with acetic acid or aniline moieties (∼0.10 molecular groups inserted per surface sulfur atom) were obtained. Analysis of the functionalization process indicated it to be enabled by the external supply of electrons from the cathodic potential, although they could also be sourced from a proper reducing agent, as well as by the presence of intrinsic defects in the 2H-phase MoS2 lattice (e.g., sulfur vacancies), where the molecular groups can bind. The acetic acid-functionalized nanosheets were tested as a non-noble metal-based catalyst for nitroarene and organic dye reduction, which is of practical utility in environmental remediation and chemical synthesis, and exhibited a markedly enhanced activity, surpassing that of other (1T- or 2H-phase) MoS2 materials and most non-noble metal catalysts previously reported for this application. The reduction kinetics (reaction order) was seen to correlate with the net electric charge of the nitroarene/dye molecules, which was ascribed to the distinct abilities of the latter to diffuse to the catalyst surface. The functionalized MoS2 catalyst also worked efficiently at realistic (i.e., high) reactant concentrations, as well as with binary and ternary mixtures of the reactants, and could be immobilized on a polymeric scaffold to expedite its manipulation and reuse.

Effect of non-oxidative plasma treatments on the surface properties of poly(p-phenylene terephthalamide) (PPTA) and poly(p-phenylene benzobisoxazole) (PBO) fibres as measured by inverse gas chromatography.

It has been shown in previous works that the interfacial adhesion in PPTA- and PBO-epoxy composites can be improved by modifying the surface properties of these high-performance fibres upon exposure to non-oxidative plasma treatments. In this work, the effects developed on both types of polymer surface were examined as a function of treatment gas nature (He or N2) and exposure time (one or four minutes) using inverse gas chromatography at infinite dilution (IGC). From the adsorption of n-alkanes, it has been proved that non-oxidative plasma treatments led to energetically heterogeneous surfaces in the case of PPTA, and to low-energy surfaces in the case of PBO. Nevertheless, it was proved with the 1-min plasma treatments (either under helium or under nitrogen) that chemical reactivity was enhanced on the PBO surface. Such a behaviour was ascribed to the presence of low-molecular weight oxidized materials. The mechanisms involved in surface activation of PPTA were not equivalent under He or N2 exposure. Nitrogen plasma exposure led to a PPTA surface that is chemically reactive as a result of polarity enhancement. Helium plasma-treated PPTA surface was characterized by the presence of branched arrangements that intensified the number of chemical contacts onto reactive sites. Finally, for both fibre sets, if the purpose is to enhance the chemical surface reactivity, it makes no sense to increase the plasma exposure time from 1 to 4 min.

Factors associated with sepsis development in 606 Spanish adult patients with cellulitis.

BACKGROUND: Cellulitis, a frequent cause of admission of adult patients to medical wards, occasionally evolves to sepsis. In this study we analyze the factors related to sepsis development. METHODS: Prospective and observational study of 606 adult patients with cellulitis admitted to several Spanish hospitals. Comorbidities, microbiological, clinical, lab, diagnostic, and treatment data were analyzed. Sepsis was diagnosed according to the criteria of the 2016 International Sepsis Definitions Conference. Multiple logistic regression modelling was performed to determine the variables independently associated with sepsis development. RESULTS: Mean age was 63.4 years and 51.8% were men. Overall 65 (10.7%) patients developed sepsis, 7 (10.8%) of whom died, but only 4 (6.2%) due to cellulitis. Drawing of blood (P < 0.0001) or any (P < 0.0001) culture, and identification of the agent (P = 0.005) were more likely among patients with sepsis. These patients had also a longer duration of symptoms (P = 0.04), higher temperature (P = 0.03), more extensive cellulitis (P = 0.02), higher leukocyte (P < 0.0001) and neutrophil (P < 0.0001) counts, serum creatinine (P = 0.001), and CRP (P = 0.008) than patients without sepsis. Regarding therapy, patients with sepsis were more likely to undergo changes in the initial antimicrobial regimen (P < 0.0001), received more antimicrobials (P < 0.0001), received longer intravenous treatment (P = 0.03), and underwent surgery more commonly (P = 0.01) than patients without sepsis. Leukocyte counts (P = 0.002), serum creatinine (P = 0.003), drawing of blood cultures (P = 0.004), change of the initial antimicrobial regimen (P = 0.007) and length of cellulitis (P = 0.009) were independently associated with sepsis development in the multivariate analysis. CONCLUSIONS: Increased blood leukocytes and serum creatinine, blood culture drawn, modification of the initial antimicrobial regimen, and maximum length of cellulitis were associated with sepsis in these patients.

Nanobiofertilization as a novel technology for highly efficient foliar application of Fe and B in almond trees.

Nanofertilization is postulated as a new technology to deal with the environmental problems caused by the intensive use of traditional fertilizers. One of the aims of this new technology is to improve foliar fertilization, which has many environmental advantages, but currently there are numerous factors that limit its efficiency. In this research, the objective was to study the potential of membrane vesicles derived from plant material as nanofertilizers of iron (Fe) and boron (B) for foliar application in almond trees (Prunus dulcis L.). The results show that the application of vesicles caused invaginations in the plasma membrane of the leaf cells. Also, the increase in leaf B and Fe was greater when these elements were applied in an encapsulated form rather than in a non-encapsulated form. The distribution of these elements in leaf tissues indicated the existence of an intracellular element transport pathway and accumulation areas, enabling greater element entry and mobility.

A direct route to activated two-dimensional cobalt oxide nanosheets for electrochemical energy storage, catalytic and environmental applications.

Two-dimensional Co3O4 nanosheets have emerged as attractive materials for use in a number of relevant technological applications. To exhibit a competitive performance in such uses, however, their structure needs to be activated, which is frequently accomplished via post-synthesis reduction strategies that introduce oxygen vacancies and increase the number of active Co(II) sites. Here, we investigate a direct route for the synthesis of activated Co3O4 nanosheets that avoids reduction post-treatments, yielding materials with a high potential towards energy- and environment-related applications. The synthesis relied on an interim amorphous cobalt oxide material with nanosheet morphology, which upon calcination afforded Co3O4 nanosheets having Co(II) sites in quantities similar to those usually found for Co3O4 nanostructures activated by reduction post-treatments. When tested as electrodes for charge storage, the nanosheets demonstrated a competitive behavior in terms of both capacity and rate capability, e.g., a gravimetric capacity of ∼293 mAh g-1 at 1 A g-1 with 57% retention at 60 A g-1 was measured for nanosheets calcined at 350 °C. The materials were shown to be efficient catalysts for the reduction of nitroarenes (4-nitrophenol and 4-nitroaniline), outperforming other Co3O4 nanostructures, as well as effective adsorbents for the removal of organic dyes (methyl orange, methylene blue) from water.

A "Nanopore Lithography" Strategy for Synthesizing Hierarchically Micro/Mesoporous Carbons from ZIF-8/Graphene Oxide Hybrids for Electrochemical Energy Storage.

Porous carbons derived from metal-organic frameworks (MOFs) are promising materials for a number of energy- and environment-related applications, but their almost exclusively microporous texture can be an obstacle to their performance in practical uses. Here, we introduce a novel strategy for the generation of very uniform mesoporosity in a prototypical MOF, namely, zeolitic imidazolate framework-8 (ZIF-8). The process, referred to as "nanopore lithography", makes use of graphene oxide (GO) nanosheets enclosing ZIF-8 particles as masks or templates for the transfer of mesoporous texture to the latter. Upon controlled carbonization and activation, nanopores created in the GO envelope serve as selective entry points for localized etching of carbonized ZIF-8, so that such nanopores are replicated in the MOF-derived carbonaceous structure. The resulting porous carbons are dominated by uniform mesopores ∼3-4 nm in width and possess specific surface areas of ∼1300-1400 m2 g-1. Furthermore, we investigate and discuss the specific experimental conditions that afford the mesopore-templating action of the GO nanosheets. Electrochemical characterization revealed an improved capacitance as well as a faster, more reversible charge/discharge kinetics for the ZIF-8-derived porous carbons obtained through nanopore lithography, relative to those for their counterparts with standard activation (no GO templating), thus indicating the potential practical advantage of the present approach in capacitive energy storage applications.

Electrochemical Exfoliation of Graphite in Aqueous Sodium Halide Electrolytes toward Low Oxygen Content Graphene for Energy and Environmental Applications.

Graphene and graphene-based materials have shown great promise in many technological applications, but their large-scale production and processing by simple and cost-effective means still constitute significant issues in the path of their widespread implementation. Here, we investigate a straightforward method for the preparation of a ready-to-use and low oxygen content graphene material that is based on electrochemical (anodic) delamination of graphite in aqueous medium with sodium halides as the electrolyte. Contrary to previous conflicting reports on the ability of halide anions to act as efficient exfoliating electrolytes in electrochemical graphene exfoliation, we show that proper choice of both graphite electrode (e.g., graphite foil) and sodium halide concentration readily leads to the generation of large quantities of single-/few-layer graphene nanosheets possessing a degree of oxidation (O/C ratio down to ∼0.06) lower than that typical of anodically exfoliated graphenes obtained with commonly used electrolytes. The halide anions are thought to play a role in mitigating the oxidation of the graphene lattice during exfoliation, which is also discussed and rationalized. The as-exfoliated graphene materials exhibited a three-dimensional morphology that was suitable for their practical use without the need to resort to any kind of postproduction processing. When tested as dye adsorbents, they outperformed many previously reported graphene-based materials (e.g., they adsorbed ∼920 mg g-1 for methyl orange) and were useful sorbents for oils and nonpolar organic solvents. Supercapacitor cells assembled directly from the as-exfoliated products delivered energy and power density values (up to 15.3 Wh kg-1 and 3220 W kg-1, respectively) competitive with those of many other graphene-based devices but with the additional advantage of extreme simplicity of preparation.

Cuidados de enfermería del niño crítico cronificado / Nursing care of the acutely and critically ill child

No disponible

Técnica quirúrgica de la resección transuretral de tumor vesical en bloque con Hybrid Knife(R) / Surgical technique for en bloc transurethral resection of bladder tumour with a Hybrid Knife(R)

Antecedentes: El cáncer vesical es la segunda malignidad más común del tracto urinario y la novena a nivel mundial, en Latinoamérica con incidencia de 5.6 por cada 100.000 habitantes por año. El 75% de casos nuevos diagnosticados son cáncer vesical no musculoinvasivos y el 25% se presenta con invasión muscular. El pilar del tratamiento del cáncer vesical no musculoinvasivo es la resección transuretral con asa. En 2013 el grupo del Dr. Mundhenk del Hospital Universitario de Tübingen, Alemania, fueron los primeros en describir el equipo Hybrid Knife(R) para realizar resección de tumor vesical en bloque con resultados funcionales y oncológicos favorables. Objetivo: Describir la técnica quirúrgica de resección de tumor vesical en bloque con Hybrid Knife(R) como alternativa de tratamiento para los tumores vesicales no musculoinvasivos. Material y métodos: Varón con tumor vesical diagnosticado por urotomografía y uretrocistoscopia de 2 × 1 cm en piso, se realizó resección transuretral de tumor vesical en bloque con Hybrid Knife(R). Resultados: Se realizó cirugía, en 35 min, con 70 watts en corte y 50 watts en coagulación, resecando y evacuando en bloque el tumor vesical incluyendo macroscópicamente capa muscular de la vejiga, sin complicaciones. Conclusión: La técnica de resección de tumor vesical en bloque con Hybrid Knife(R) es una alternativa eficaz a la resección transuretral con asa bipolar. La resección con Hybrid Knife(R) es un procedimiento con escaso sangrado, buena visión quirúrgica, minimizando el riesgo de perforación vesical o implantes tumorales con mayor facilidad para lograr determinar positividad de proceso neoplásico, infiltración vascular e invasión a músculo vesical en estudio histopatológico

Background: Bladder cancer is the second most common malignancy of the urinary tract and the 9 th worldwide. Latin American has an incidence of 5.6 per 100,000 inhabitants per year. Seventy-five percent of newly diagnosed cases are nonmuscle invasive bladder cancer, and 25% of cases present as muscle invasive. The mainstay of treatment for nonmuscle invasive bladder cancer is loop transurethral resection. In 2013, the group led by Dr Mundhenk of the University Hospital of Tübingen, Germany, was the first to describe the Hybrid Knife(R) equipment for performing en bloc bladder tumour resection, with favourable functional and oncological results. Objective: To describe the surgical technique of en bloc bladder tumour resection with a Hybrid Knife(R) as an alternative treatment for nonmuscle invasive bladder tumours. Material and methods A male patient was diagnosed by urotomography and urethrocystoscopy with a bladder tumour measuring 2 × 1 cm on the floor. En bloc transurethral resection of the bladder tumour was performed with a Hybrid Knife(R). Results: Surgery was performed for 35 min, with 70 watts for cutting and 50 watts for coagulation, resecting and evacuating en bloc the bladder tumour, which macroscopically included the muscle layer of the bladder. There were no complications. Conclusion: The technique of en bloc bladder tumour resection with Hybrid Knife® is an effective alternative to bipolar loop transurethral resection. Resection with a Hybrid Knife(R) is a procedure with little bleeding and good surgical vision and minimises the risk of bladder perforation and tumour implants. The procedure facilitates determining the positivity of the neoplastic process, vascular infiltration and bladder muscle invasion in the histopathology study

Electrolytic exfoliation of graphite in water with multifunctional electrolytes: en route towards high quality, oxide-free graphene flakes.

Electrolytic--usually referred to as electrochemical--exfoliation of graphite in water under anodic potential holds enormous promise as a simple, green and high-yield method for the mass production of graphene, but currently suffers from several drawbacks that hinder its widespread adoption, one of the most critical being the oxidation and subsequent structural degradation of the carbon lattice that is usually associated with such a production process. To overcome this and other limitations, we introduce and implement the concept of multifunctional electrolytes. The latter are amphiphilic anions (mostly polyaromatic hydrocarbons appended with sulfonate groups) that play different relevant roles as (1) an intercalating electrolyte to trigger exfoliation of graphite into graphene flakes, (2) a dispersant to afford stable aqueous colloidal suspensions of the flakes suitable for further use, (3) a sacrificial agent to prevent graphene oxidation during exfoliation and (4) a linker to promote nanoparticle anchoring on the graphene flakes, yielding functional hybrids. The implementation of this strategy with some selected amphiphiles even furnishes anodically exfoliated graphenes of a quality similar to that of flakes produced by direct, ultrasound- or shear-induced exfoliation of graphite in the liquid phase (i.e., almost oxide- and defect-free). These high quality materials were used for the preparation of catalytically efficient graphene-Pt nanoparticle hybrids, as demonstrated by model reactions (reduction of nitroarenes). The multifunctional performance of these electrolytes is also discussed and rationalized, and a mechanistic picture of their oxidation-preventing ability is proposed. Overall, the present results open the prospect of anodic exfoliation as a competitive method for the production of very high quality graphene flakes.

Investigating the Dispersion Behavior in Solvents, Biocompatibility, and Use as Support for Highly Efficient Metal Catalysts of Exfoliated Graphitic Carbon Nitride.

The liquid-phase exfoliation of graphitic carbon nitride (g-C3N4) to afford colloidal dispersions of two-dimensional flakes constitutes an attractive route to facilitate the processing and implementation of this novel material toward different technological applications, but quantitative knowledge about its dispersibility in solvents is lacking. Here, we investigate the dispersion behavior of exfoliated g-C3N4 in a wide range of solvents and evaluate the obtained results on the basis of solvent surface energy and Hildebrand/Hansen solubility parameters. Estimates of the three Hansen parameters for exfoliated g-C3N4 from the experimentally derived data yielded δD ≈ 17.8 MPa(1/2), δP ≈ 10.8 MPa(1/2), and δH ≈ 15.4 MPa(1/2). The relatively high δH value suggested that, contrary to the case of other two-dimensional materials (e.g., graphene or transition metal dichalcogenides), hydrogen-bonding plays a substantial role in the efficient interaction, and thus dispersibility, of exfoliated g-C3N4 with solvents. Such an outcome was attributed to a high density of primary and/or secondary amines in the material, the presence of which was associated with incomplete condensation of the structure. Furthermore, cell proliferation tests carried out on thin films of exfoliated g-C3N4 using murine fibroblasts suggested that this material is highly biocompatible and noncytotoxic. Finally, the exfoliated g-C3N4 flakes were used as supports in the synthesis of Pd nanoparticles, and the resulting hybrids exhibited an exceptional catalytic activity in the reduction of nitroarenes.

Achieving extremely concentrated aqueous dispersions of graphene flakes and catalytically efficient graphene-metal nanoparticle hybrids with flavin mononucleotide as a high-performance stabilizer.

The stable dispersion of graphene flakes in an aqueous medium is highly desirable for the development of materials based on this two-dimensional carbon structure, but current production protocols that make use of a number of surfactants typically suffer from limitations regarding graphene concentration or the amount of surfactant required to colloidally stabilize the sheets. Here, we demonstrate that an innocuous and readily available derivative of vitamin B2, namely the sodium salt of flavin mononucleotide (FMNS), is a highly efficient dispersant in the preparation of aqueous dispersions of defect-free, few-layer graphene flakes. Most notably, graphene concentrations in water as high as ∼50 mg mL(-1) using low amounts of FMNS (FMNS/graphene mass ratios of about 0.04) could be attained, which facilitated the formation of free-standing graphene films displaying high electrical conductivity (∼52000 S m(-1)) without the need of carrying out thermal annealing or other types of post-treatment. The excellent performance of FMNS as a graphene dispersant could be attributed to the combined effect of strong adsorption on the sheets through the isoalloxazine moiety of the molecule and efficient colloidal stabilization provided by its negatively charged phosphate group. The FMNS-stabilized graphene sheets could be decorated with nanoparticles of several noble metals (Ag, Pd, and Pt), and the resulting hybrids exhibited a high catalytic activity in the reduction of nitroarenes and electroreduction of oxygen. Overall, the present results should expedite the processing and implementation of graphene in, e.g., conductive inks, composites, and hybrid materials with practical utility in a wide range of applications.

Synthesis, characterization and dye removal capacities of N-doped mesoporous carbons.

Nitrogen-doped ordered mesoporous carbons were synthesized by chemical vapor deposition, using acetonitrile as carbon and nitrogen source and SBA-15 as mesoporous silica template. Their porous texture, structural order and surface chemistry were studied as a function of the experimental conditions (acetonitrile stream concentration and deposition time). A non-doped ordered mesoporous carbon was also prepared by the same procedure using propylene as carbon source. Methylene blue, methyl orange and fuchsin acid were selected as probe molecules to investigate the dye adsorption behavior on the ordered mesoporous carbons. Both N-doped and non-doped ordered mesoporous carbons adsorbed large amounts of these three dyes demonstrating the importance of mesoporosity, especially for the adsorption of larger dyes (e.g. fuchsin acid). The presence of nitrogen functional groups was detrimental for the adsorption of the basic dye (methylene blue). On the other hand, the nitrogen functionalities improved the adsorption kinetics for both acid and basic dyes, and the N-doped samples achieved 100% of their maximum adsorption capacities in less than 15 min.

Activated carbon fibers with a high heteroatom content by chemical activation of PBO with phosphoric acid.

The preparation of activated carbon fibers (ACFs) by phosphoric acid activation of poly(p-phenylene benzobisoxazole) (PBO) fibers was studied, with particular attention to the effects of impregnation ratio and carbonization temperature on porous texture. Phosphoric acid has a strong effect on PBO degradation, lowering the temperature range at which the decomposition takes place and changing the number of mass loss steps. Chemical analysis results indicated that activation with phosphoric acid increases the concentration of oxygenated surface groups; the resulting materials also exhibiting high nitrogen content. ACFs are obtained with extremely high yields; they have well-developed porosity restricted to the micropore and narrow mesopore range and with a significant concentration of phosphorus incorporated homogeneously in the form of functional groups. An increase in the impregnation ratio leads to increases in both pore volume and pore size, maximum values of surface area (1250 m(2)/g) and total pore volume (0.67 cm(3)/g) being attained at the highest impregnation ratio (210 wt % H(3)PO(4)) and lowest activation temperature (650 °C) used; the corresponding yield was as large as 83 wt %. The obtained surface areas and pore volumes were higher than those achieved in previous works by physical activation with CO(2) of PBO chars.

Surface modification of high-performance polymeric fibers by an oxygen plasma. A comparative study of poly(p-phenylene terephthalamide) and poly(p-phenylene benzobisoxazole).

Poly(p-phenylene terephthalamide) (PPTA) and poly(p-phenylene benzobisoxazole) (PBO) fibers were exposed to an oxygen plasma under equivalent conditions. The resulting changes in the surface properties of PPTA and PBO were comparatively investigated using inverse gas chromatography (IGC) and atomic force microscopy (AFM). Both non-polar (n-alkanes) and polar probes of different acid-base characteristics were used in IGC adsorption experiments. Following plasma exposure, size-exclusion phenomena, probably associated to the formation of pores (nanoroughness), were detected with the largest n-alkanes (C(9) and C(10)). From the adsorption of polar probes, an increase in the number or strength of the acidic and basic sites present at the fiber surfaces following plasma treatment was detected. The effects of the oxygen plasma treatments were similar for PPTA and PBO. In both cases, oxygen plasma introduces polar groups onto the surfaces, involving an increase in the degree of surface nanoroughness. AFM measurements evidenced substantial changes in the surface morphology at the nanometer scale, especially after plasma exposure for a long time. For the PBO fibers, the outermost layer - contaminant substances - was removed thanks to the plasma treatment, which indicates that this agent had a surface cleaning effect.

Surface chemical modifications induced on high surface area graphite and carbon nanofibers using different oxidation and functionalization treatments.

Two graphitic carbon materials with different edge to basal plane ratio, high surface area graphite (HSAG) and graphitized carbon nanofibers (CNFs), were oxidized by two methods, aqueous-HNO(3) wet oxidation and oxygen plasma oxidation. Characterization of the materials by temperature-programmed desorption, thermogravimetry and X-ray photoelectron and Raman spectroscopies indicated that the amount and nature of oxygen surface groups introduced depended on the oxidation method and on the structure of the original material. While surface sites within the layers were only oxidized by oxygen plasma, surface sites at the edges of graphene layers were oxidized by both treatments being the wet oxidation more effective. Modification of the oxidized materials with a diamine or a triamine molecule resulted in the formation of ammonium carboxylate salt species on the carbon surface.

A comparison between physically and chemically driven etching in the oxidation of graphite surfaces.

The etching of graphite surfaces by two different types of oxidative treatments, namely dielectric barrier discharge (DBD) air plasma and ultraviolet-generated ozone (UVO), has been investigated and compared by means of scanning tunneling microscopy (STM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Although the attack is initiated in both cases with the formation of individual, isolated atomic-scale defects (in particular, atomic vacancies), its subsequent evolution indicated that different mechanisms drive the surface modification in the two types of treatment, which greatly differ in etching selectivity. Thus, physical processes (i.e., ion bombardment) dominate the attack by DBD air plasma, which are not present in the case of UVO oxidation. The effects of the different etching mechanisms on the graphite surface structure, as visualized by STM down to the atomic scale, are discussed and found to be consistent with the Raman spectroscopy and XPS data. This type of information can be relevant when selecting the most appropriate type of surface modification of carbon materials for specific purposes.

Atomic force and scanning tunneling microscopy imaging of graphene nanosheets derived from graphite oxide.

Graphene nanosheets produced in the form of stable aqueous dispersions by chemical reduction of graphene oxide and deposited onto graphite substrates have been investigated by atomic force and scanning tunneling microscopy (AFM/STM). The chemically reduced graphene oxide nanosheets were hardly distinguishable from their unreduced counterparts in the topographic AFM images. However, they could be readily discriminated through phase imaging in the attractive regime of tapping-mode AFM, probably because of differences in hydrophilicity arising from their distinct oxygen contents. The chemically reduced nanosheets displayed a smoothly undulated, globular morphology on the nanometer scale, with typical vertical variations in the subnanometer range and lateral feature sizes of approximately 5-10 nm. Such morphology was attributed to be the result of significant structural disorder in the carbon skeleton, which originates during the strong oxidation that leads to graphene oxide and remains after chemical reduction. Direct evidence of structural disorder was provided by atomic-scale STM imaging, which revealed an absence of long-range periodicity in the graphene nanosheets. Only structured domains a few nanometers large were observed instead. Likewise, the nanosheet edges appeared atomically rough and ill-defined, though smooth on the nanometer scale. The unreduced graphene oxide nanosheets could only be imaged by STM at very low tunneling currents (approximately 1 pA), being visualized in some cases with inverted contrast relative to the graphite substrate, a result that was attributed to their extremely low conductivity. Complementary characterization of the unreduced and chemically reduced nanosheets was carried out by thermogravimetric analysis as well as UV-visible absorption and X-ray photoelectron and Raman spectroscopies. In particular, the somewhat puzzling Raman results were interpreted to be the result of an amorphous character of the graphene oxide material.

Graphene oxide dispersions in organic solvents.

The dispersion behavior of graphene oxide in different organic solvents has been investigated. As-prepared graphite oxide could be dispersed in N, N-dimethylformamide, N-methyl-2-pyrrolidone, tetrahydrofuran, and ethylene glycol. In all of these solvents, full exfoliation of the graphite oxide material into individual, single-layer graphene oxide sheets was achieved by sonication. The graphene oxide dispersions exhibited long-term stability and were made of sheets between a few hundred nanometers and a few micrometers large, similar to the case of graphene oxide dispersions in water. These results should facilitate the manipulation and processing of graphene-based materials for different applications.

Tuning of texture and surface chemistry of carbon xerogels.

The influence of different activation processes on the textural and surface chemical properties of carbon xerogels was studied. Carbon xerogels were prepared by the conventional sol-gel approach using resorcinol and formaldehyde; two different pHs of sol-gel processing led to carbon materials with distinct pore size distributions. The materials were subjected to controlled activation by three different methods: activation by oxygen plasma, activation by HNO(3), and activation by diluted air. Treatments with HNO(3) and diluted air created oxygen groups on the external surface as well as inside the pore channels, whereas plasma is more suitable for introducing oxygen groups selectively on the external surface. Nevertheless, it was shown that samples with wider pores can be oxidized to some extent on the pore interiors by plasma. Significant changes in total surface area by air activation were observed.